URLs look like this: (file: and ftp: URLs are synonymous.)
The first part of the URL, before the colon, specifies the access method. The part of the URL after the colon is interpreted specific to the access method. In general, two slashes after the colon indicate a machine name (machine:port is also valid).
When you are told to "check out this URL", what to do next depends on your browser; please check the help for your particular browser. For the line-mode browser at CERN, which you will quite possibly use first via telnet, the command to try a URL is "GO URL" (substitute the actual URL of course). In Lynx you just select the "GO" link on the first page you see; in graphical browsers, there's usually an "Open URL" option in the menus.